Usage on Efecto anomérico. Usage on Anomeerinen efekti. Usage on Effetto anomerico. Breve semblanza de Eusebio Juaristi en ocasión del XV Aniversario del descubrimiento del efecto anomérico en el segmento S-C-P. Article (PDF Available). Translation for: ‘efecto (m.) biológico’ in Spanish->English efecto (m.) anódico · anode effect, anodic effect · efecto (m.) anomérico · anomeric effect · efecto (m.).
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If you are searching for a word in Japanese Kanji dictionary and not receiving any results, try without Kana term in brackets.
Chemical glycosylation — A chemical glycosylation reaction involves the coupling of a sugar to a glycosyl acceptor forming a glycoside.
Afterwards, you simply type the chosen keyword in the address bar to start the search in the chosen dictionary. I do this in my spare time. In organic chemistrythe anomeric effect or Edward-Lemieux effect is a stereoelectronic effect that describes the tendency of heteroatomic substituents adjacent to a heteroatom within a cyclohexane ring to prefer the “axial” orientation instead of the less hindered “equatorial” orientation that would be expected from steric considerations.
In Chrome, first click on a language pair and change the search keyword in the field ‘Keyword’ to a keyword eg: Edward in ; at that time, N. Total number of language pairs: Glucose — This article is about the naturally occurring D form of glucose. To contact me for any reason please send me an email to tkuzmic at gmail dot com.
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For the same reason the Chinese dictionary contains traditional and simplified Chinese terms on one side and Pinyin and English terms on the other. For example, a small molecule that exhibit the anomeric effect and that is often anomegico for theoretical studies is dimethoxymethane. In the diagram, both anomers of glucopyranose are identical, except that the “beta” anomer on the right has an OH group pointing up equatorially in the lower right-hand corner of the figure, whereas the “alpha” anomer on anomercio left has that OH group pointing down axially.
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Look at other dictionaries: Continuing to use this site, you agree with this. Some of the words may be incorrectly translated or mistyped. The anomeric effect can be generalized to any system with the general formula R—Y—C—Z, where Y is an atom with one or more electronic lone pair s, and Z is an electronegative atom. The simplest explanation is that the equatorial configuration has the dipole s involving both heteroatoms partially aligned, and therefore repelling each other.
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efecto (m.) biológico | EUdict | Spanish>English
Mark and share Search through all dictionaries Translate… Search Internet. If you are unable to add a bookmarklet in Mozilla Firefox according to the instructions above, there is another way; right click on a link and select Bookmark this link…. Lemieux began to study the anomerization equilibria of the fully acetylated derivatives of several aldohexopyranoses.
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I am responsible for the concept, design, programming and development. My name is Tomislav Kuzmic, I live in Croatia and this site is my personal project. Electronic effect — An electronic effect influences the structure, reactivity, or properties of molecule but is neither a traditional bond nor a steric effect. The most common way is by word input you must know which language the word is in but you can also use your browser’s search box and bookmarklets or favelets.
To add EUdict alongside Google, Yahoo! Glycosidic bond — In chemistry, a glycosidic bond is a type of covalent bond that joins a carbohydrate sugar molecule to another group, which may or may not be another carbohydrate.
There is a way to enable word translation from any page: Spanish – English Results for: By contrast the axial configuration has these dipoles roughly opposing, thus representing a more stable and lower energy state. In this general case, the molecule need not be cyclic. If you want to type a character which isn’t on your keyboard, simply pick it from a list of special characters.
InBox’s molecular modeling studies of saccharides, and analysis of crystallographic data of monosaccharides from the Cambridge Crystallographic Database, using the molecular mechanics based program STR3DI32, resulted in a refinement of this dipolar hypothesis by showing that the dipolar repulsions originally suggested, above, were reinforced by stabilizing, and significant, C-H Let me take this chance to thank all who contributed to the making of these dictionaries and improving the site’s quality:.
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The term “anomeric effect” was introduced in Anomeric effect In organic chemistrythe anomeric effect or Edward-Lemieux effect is a stereoelectronic effect that describes the tendency anomefico heteroatomic substituents adjacent to a heteroatom within a cyclohexane ring to prefer the “axial” orientation instead of the less hindered “equatorial” orientation that would be expected from steric considerations.
If you are searching for a word in the Chinese dictionary and not receiving any results, try without Pinyin term in brackets. We are using cookies for the best presentation of our efrcto. Dictionaries exportcreated on PHP. Look at the complete list of languages: However, it is well known that when the exocyclic atoms bear lone pairs of electrons, the anomeric anomerixo is maximal.